Journal of Organometallic Chemistry p. 329 - 336 (1986)
Update date:2022-08-04
Topics:
Pasman, P.
Snel, J. J. M.
Deprotonation of cis-(η5-C5H5)(CO)2Re(SiPh3)H by neopentyllithium at -78 deg C in THF gives an anionic species, which is shown by spectroscopic and chemical methods to be ((η5-C5H4(SiPh3))(CO)2ReH)Li.Its formation is explained by initial deprotonation of the cyclopentadienyl ligand, followed by an intramolecular silyl-group migration.Protonation of the anion at room temperature gives trans-(η5-C5H4(SiPh3))(CO)2ReH2.The latter isomerizes to the trans dihydride complex at room temperature (t1/2 12 h).
View MoreContact:86-513-84128750/13773795976
Address:No.48.Youyi West Road ,Rudong Development Zone,Jiangsu Province,China
Engineering Research Center of Pesticide, Heilongjiang Province
Contact:+86-451-86609001
Address:No.74 of Xuefu Road, Nangang District,
Shandong Xingshun New Material Co., Ltd.
website:http://www.sd-xingshun.com
Contact:+86-519-86461196
Address:Middle of Luhua East Road, Dingtao District
SHAANXI TOP PHARM CHEMICAL CO.LTD
Contact:+86-029-85733403
Address:No.108 ,west sector,south er huan,xi'an,china
Suzhou SuKaiLu Chemical Technology Co., Ltd.
Contact:+86-512-62766020
Address:Floor 4, Building 1, Xinyi Pharmaceutical Valley Wisdom Industrial Park, 415 Changyang Street, Suzhou Industrial Park, Jiangsu Province
Doi:10.1007/s00044-007-9068-x
(2008)Doi:10.1021/jm00343a004
(1982)Doi:10.1055/s-1986-31483
(1986)Doi:10.1016/j.tet.2015.09.003
(2015)Doi:10.1021/ol801512q
(2008)Doi:10.1021/ol400360g
(2013)
