Journal of Organometallic Chemistry p. 329 - 336 (1986)
Update date:2022-08-04
Topics:
Pasman, P.
Snel, J. J. M.
Deprotonation of cis-(η5-C5H5)(CO)2Re(SiPh3)H by neopentyllithium at -78 deg C in THF gives an anionic species, which is shown by spectroscopic and chemical methods to be ((η5-C5H4(SiPh3))(CO)2ReH)Li.Its formation is explained by initial deprotonation of the cyclopentadienyl ligand, followed by an intramolecular silyl-group migration.Protonation of the anion at room temperature gives trans-(η5-C5H4(SiPh3))(CO)2ReH2.The latter isomerizes to the trans dihydride complex at room temperature (t1/2 12 h).
View Morewebsite:http://www.antaibio.com
Contact:0086-21-65663057
Address:Room 2108, Building 2，No. 489 Zhengli Road，200433
Zhuhai Rundu Pharmaceutical co.,Ltd
Contact:+86-756-7630755
Address:No.6,North Airport Road,Sanzao Town,Jinwan District
Yantai Derun Liquid Crystal Materials Co. Ltd.
website:http://www.ytderun.com
Contact:86-535-6300169
Address:ROOM 90, XIANGFU STREET, FUSHAN NEW-HIGH-TECH IDUSTRY ZONE, YANTAI
Xian Changyue Biological Technology Co., Ltd.
website:https://www.xachangyue.com/
Contact:+86-029-88211911
Address:Keji Road NO.70
shanghai jinshan pharmaceutical Co.,Ltd
Contact:021-57363011，13681638167
Address:No. 7966 Tingfeng Road,Jinshan,Shanghai,China
Doi:10.1007/s00044-007-9068-x
(2008)Doi:10.1021/jm00343a004
(1982)Doi:10.1055/s-1986-31483
(1986)Doi:10.1016/j.tet.2015.09.003
(2015)Doi:10.1021/ol801512q
(2008)Doi:10.1021/ol400360g
(2013)
