Journal of Organic Chemistry p. 3323 - 3326 (1987)
Update date:2022-08-04
Topics:
Collado, Isidro G.
Macias, Francisco A.
Massanet, Guillermo M.
Molinillo, Jose Maria G.
Luis, Francisco R.
Subexpinnatin C (5), a secondary metabolite isolated from Centaurea canariensis Brouss. (var. subexpinnata Burch.), has been regio- and stereoselectively synthesized from deacylsubexpinnatin (11).This transformation involves a photoaddition reaction and a new method of obtaining the oxetane ring.
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