DARSTELLUNG UND REAKTIONEN VON DIPHOSPHEN-KOMPLEXEN RP=PR3 (M = Cr, Mo, W)

DOI: 10.1016/0022-328X(86)80149-8

Source and publish data:

Journal of Organometallic Chemistry p. 309 - 322 (1986)

Update date:2022-08-04

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Authors:

Huttner, Gottfried

Borm, Jutta

Zsolnai, Laszlo

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Article abstract of DOI:10.1016/0022-328X(86)80149-8

Decarbonyldimetallates Na2M2(CO)10 (M=Cr, Mo, W) react with dihalophosphanes, (R)P(Cl)2, to yield trinuclear diphosphene complexes of the form RP=PR3.The by-products of these reactions are diphosphane- and phosphido-bridged complexes.The trinuclea

Full text of DOI:10.1016/0022-328X(86)80149-8

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