Synthesis and Cycloaddition Reactions of Homoadamantanocyclopentadienones. A Facile Route to -Fused Homoadamantanobenzene Derivatives

DOI: 10.1021/jo00380a004

Source and publish data:

Journal of Organic Chemistry p. 496 - 500 (1987)

Update date:2022-08-04

Topics:

Authors:

Eguchi, Shoji

Ishiura, Kazushige

Noda, Tomokazu

Sasaki, Tadashi

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Article abstract of DOI:10.1021/jo00380a004

2',5'-Disubstituted homoadamantano<4,5-c>cyclopentadienones 4a-c were obtained by base-catalyzed condensations of homoadamantane-4,5-dione with 3-pentanone, 1,3-diphenylacetone, and dimethyl 3-oxoglutarate.Diels-Alder reactions of 4a-c with acetylenic die

Full text of DOI:10.1021/jo00380a004

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