EINFACHE, REGIOSPECIFISCHE SYNTHESE VON CYCLOALKENONEN AUS LACTONEN

DOI: 10.1016/S0040-4039(01)84590-1

Source and publish data:

Tetrahedron Letters p. 6329 - 6332 (1985)

Update date:2022-07-31

Topics:

Authors:

Altenbach, Hans-Josef

Holzapfel, Winfried

Smerat, Gerd

Finkler, Stefan H.

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Article abstract of DOI:10.1016/S0040-4039(01)84590-1

The reaction of lithiumalkylphosphonates with γ- or δ-lactones followed by oxidation leads to 2,5- or 2,6-dioxophosphonates, which can be cyclized to cyclopentanones or cyclohexanones, respectively, constituting an easy, regiospecific route to cycloalkanones from lactones.

Full text of DOI:10.1016/S0040-4039(01)84590-1

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