γ-ALKYLATION OF α'-(PHENYLSULFONYL)-α,β-UNSATURATED KETONES: THE TRIANION IMPERATIVE

DOI: 10.1016/S0040-4039(00)84627-4

Source and publish data:

Tetrahedron Letters p. 2725 - 2726 (1986)

Update date:2022-08-05

Topics:

Authors:

Lansbury, Peter T.

Spagnuolo, Ciro J.

Grimm, Erich L.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)84627-4

γ-alkylation of the title compounds with primary alkyl iodides is possible only when both α'-protons are first ionized with excess lithium diisopropylamide.

Full text of DOI:10.1016/S0040-4039(00)84627-4

Products guided by the article

Product name:1-benzenesulfonyl-4-methylpent-3-en-2-one

Cas No:107006-44-0

R&D Labs maybe for 107006-44-0

SICHUAN TONGSHENG AMINOACID CO.LTD

website:http://www.aminoacid.cc

Contact:86-838-2274206/2850606

Address:Room 1-11-1,No.19 of North TianShan Road,Deyang,Sichuan China
YingYing Pharmaceutical Co.,Ltd

Contact:86-18854126208

Address:55#, yingxiongshan road
Tianjin Emulsion Science&Technology Development Co.,Ltd

Contact:13901380442

Address:Vake Garden New Town New Yi Bai Road Beichen District Tianjin,China
xuri chemicals co., ltd

Contact:86-516-66656369

Address:The west road of Huaihai, Xuzhou, China
Hubei Lingsheng Pharmaceuticals Co., Ltd.

Contact:+86-0710-3538058

Address:Xiangyang City Xiangcheng Economic Development Zone, Hubei Province

Relevant to this article

Catalytic enantioselective trapping of an alcoholic oxonium ylide with aldehydes: Rh^II/Zr^IV-co-catalyzed three-component reactions of aryl diazoacetates, benzyl alcohol, and aldehydes

Doi:10.1002/anie.200801510
(2008)
Doi:10.1007/s00402-002-0396-5
(1954)
Depropargylation under palladium-copper catalysis: Synthesis of diaryl sulfides

Doi:10.1016/S0040-4020(01)00527-0
(2001)
Synthesis and biological evaluation of resveratrol and analogues as apoptosis-inducing agents

Doi:10.1021/jm030785u
(2003)
Reaction of bis(pyrazol-1-yl)methanes modified by organotin groups on the methine carbon with W(CO)₅THF to give novel heterodinuclear organometallic complexes

Doi:10.1021/om030221o
(2003)
Preparation of α,n-dilithiotoluene equivalents. Synthesis of tamoxifen

Doi:10.1016/S0040-4020(03)00428-9
(2003)

Article Doi