Syntheses of Cyclopentene-Fused Polynuclear Aromatic Hydrocarbons

DOI: 10.1021/jo00383a021

Source and publish data:

Journal of Organic Chemistry p. 1284 - 1288 (1987)

Update date:2022-07-30

Topics:

Authors:

Chung, Ying-Sheng

Kruk, Henry

Barizo, Ophelia M.

Katz, Morris

Lee-Ruff, Edward

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Article abstract of DOI:10.1021/jo00383a021

Regioselective α or β ring opening of bicyclic α-arylcyclobutanones permits the synthesis of linear and angular cyclopentene-fused polynuclear aromatic hydrocarbons (PAH), respectively.The syntheses of the cyclopentene-fused PAHs, aceanthrylene, acephenanthrylene, benzaceanthrylene, and benzacephenanthrylene are detailed utilizing this novel methodology.

Full text of DOI:10.1021/jo00383a021

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