Synthesis, determination of the absolute stereochemistry, and evaluations at the nicotinic acetylcholine receptors of a hydroxyindolizidine alkaloid from the ant Myrmicaria melanogaster

DOI: 10.3987/COM-08-S(D)16

Source and publish data:

Heterocycles p. 565 - 571 (2009)

Update date:2022-07-30

Topics:

Authors:

Zhou, Dejun

Toyooka, Naoki

Nemoto, Hideo

Yamaguchi, Kaoru

Tsuneki, Hiroshi

Wada, Tsutomu

Sasaoka, Toshiyasu

Sakai, Hideki

Tezuka, Yasuhiro

Kadota, Shigetoshi

Jones, Tappey H.

Garraffo, H. Martin

Spande, Thomas F.

Daly, John W.

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Article abstract of DOI:10.3987/COM-08-S(D)16

The first chiral synthesis of new hydroxyindolizidine alkaloid (1) detected in the ant Myrmicaria melanogaster has been achieved, and its absolute stereochemistry was determined to be 3S, 5R, 8S, 9S by the present chiral synthesis.

Full text of DOI:10.3987/COM-08-S(D)16

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