Homolytic C-Alkylation of Aldoximes

DOI: 10.1055/s-1986-31677

Source and publish data:

Synthesis p. 473 - 474 (1986)

Update date:2022-08-03

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Authors:

Citterio, Attilio

Filippini, Lucio

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Article abstract of DOI:10.1055/s-1986-31677

Thermal decomposition of alkyl peresters in hydrogen donor solvents (cycloalkanes or ethers) in the presence of aldoximes affords (C-1)-alkylated products.The reaction is favored by electron-withdrawing substituents on the oxime and involves free C-radica

Full text of DOI:10.1055/s-1986-31677

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