ASYMMETRIC INDUCTION TO SULFUR ATOM: STEREOCONTROLLED S-OXIDATION OF THIAZOLIDINES

DOI: 10.1016/S0040-4039(00)84804-2

Source and publish data:

Tetrahedron Letters p. 3391 - 3394 (1986)

Update date:2022-08-04

Topics:

Authors:

Ando, Wataru

Huang, Liren

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Article abstract of DOI:10.1016/S0040-4039(00)84804-2

Oxidation of (2R,4R)-2,4-disubstituted thiazolidines with m-CPBA affords the trans sulfoxide exclusively.Oxidation of (2R,4R)-4-hydroxymethyl thiazolidines with Ti(OiPr)4/TBHP, however, favors to give the cis sulfoxide.

Full text of DOI:10.1016/S0040-4039(00)84804-2

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