Synlett p. 1865 - 1869 (2008)
Update date:2022-08-04
Topics:
Knobloch, Eva
Brückner, Reinhard
β-Keto[2-(trimethylsilyl)ethyl esters] are dealkoxycarbonylated at 50 °C by 0.75 equivalents of Bu4N+F -·3H2O in THF. This reaction proceeds chemoselectively in the presence of β-keto(methyl esters), β-keto(tert-butyl esters), β-keto(allyl esters), or β-keto(benzyl esters) as revealed in intermolecular competition experiments. Georg Thieme Verlag Stuttgart.
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Doi:10.3987/COM-08-S(N)26
(2008)Doi:10.1021/ic801317x
(2008)Doi:10.1002/pola.24156
(2010)Doi:10.1039/c2nj40577f
(2013)Doi:10.1016/S0040-4039(00)84629-8
(1986)Doi:10.1021/ol015897z
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