A Synthetic Approach to (-)-Quassimarin Based on Intramolecular Diels-Alder Strategy

DOI: 10.1021/jo00235a011

Source and publish data:

Journal of Organic Chemistry p. 5704 - 5714 (1987)

Update date:2022-08-03

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Authors:

Shishido, Kozo

Takahashi, Kazuyuki

Fukumoto, Keiichiro

Kametani, Tetsuji

Honda, Toshio

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Article abstract of DOI:10.1021/jo00235a011

A novel approach to the tetracyclic precursor 32 for the total synthesis of (-)-quassimarin based on an intramolecular Diels-Alder strategy is described.The key tricyclic species 22 was constructed from the triene 6 via a highly endo-selective intramolecu

Full text of DOI:10.1021/jo00235a011

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