1,3-SYN DIASTEREOSELECTIVE REDUCTION OF β-HYDROXYKETONES WITH DIISOBUTYLALUMINUM HYDRIDE AND TRIBUTYLTIN HYDRIDE

DOI: 10.1016/S0040-4039(00)84703-6

Source and publish data:

Tetrahedron Letters p. 3009 - 3012 (1986)

Update date:2022-08-03

Topics:

Authors:

Kiyooka, Syun-ichi

Kuroda, Hisanori

Shimasaki, Yayoi

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Article abstract of DOI:10.1016/S0040-4039(00)84703-6

1,3-Syn diastereofacial selectivity (<*>12 : 1) has been achieved in a facile reduction of β-hydroxyketones with DIBAL-H.Tributyltin hydride also has shown 1,3-syn selectivity.

Full text of DOI:10.1016/S0040-4039(00)84703-6

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