Chromium and Tungsten Pentacarbonyl Groups as Reactivity and Selectivity Auxiliaries in Cycloaddition of Alkynyl Fischer Carbene Complexes with N-Alkyl Nitrones

DOI: 10.1021/jo00111a036

Source and publish data:

Journal of Organic Chemistry p. 1741 - 1747 (1995)

Update date:2022-08-04

Topics:

Authors:

Chan, Kin Shing

Yeung, Ming Lok

Chan, Wai-kin

Wang, Ru-Ji

Mak, Thomas C. W.

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Article abstract of DOI:10.1021/jo00111a036

Alkynyl Fischer carbene complexes were found to undergo chemoselective, regioselective, and rate-enhanced 1,3-dipolar cycloaddition with nitrones to give 2,3-dihydroisoxazole carbene complexes in excellent yields.These alkynyl complexes can serve as synth

Full text of DOI:10.1021/jo00111a036

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