Journal of Organometallic Chemistry p. C35 - C38 (1986)
Update date:2022-08-04
Topics:
Furber, Mark
Taylor, Richard J. K.
Burford, S. Cliff
2,4'-Dilithiophenylethyne, prepared by treatment of 4-bromophenylethyne with two equivalents of butyllithium, reacts selectively with electrophilic reagents at the 4'-position provided the correct temperature and solvent combination are employed.The successive addition of two different electrophiles gives the 2,4'-dialkylated product in a regioselective manner.
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