Synthesis of Macrocyclic Terpenoids by Intramolecular Cyclization. 12. Total Synthesis of Methyl Ceriferate I, a 14-Membered Ring Sesterterpene from Scale Insects

DOI: 10.1021/jo00242a018

Source and publish data:

Journal of Organic Chemistry p. 1437 - 1441 (1988)

Update date:2022-09-26

Topics:

Authors:

Kodama, Mitsuaki

Shiobara, Yoshinori

Sumitomo, Hisako

Fukuzumi, Kazuyoshi

Minami, Hiroyuki

Miyamoto, Yasuko

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00242a018

Total synthesis of (+/-)-methyl ceriferate I (6), the methyl ester of a cembrane-type sesterterpene isolated from the wax of scale insects, was achieved by means of Wadsworth-Emmons olefination as key step.Three segments, 9, 10, and 11, were connected to

Full text of DOI:10.1021/jo00242a018

Products guided by the article

Product name:2-((3E,7E)-10-Benzyloxy-3,7-dimethyl-deca-3,7-dienyl)-[1,3]dioxolane

Cas No:107553-96-8

R&D Labs maybe for 107553-96-8

SYN Pharma Co., Ltd

Contact:86-21 60347964

Address:No.1304, West Meilong Road, Minhang District, Shanghai, China
Eastar Chemical Corporation

website:http://www.eastarchem.com/

Contact:1-800-898-2436

Address:1215 K Street, STE 1700
Guangzhou Shiny Co., Ltd.

website:https://www.sinoshiny.com/products

Contact:+86-20-62802632;62802633

Address:Room 330 GIGCAS Building,No.511 Kehua Street,Tianhe District
Wuhan Kemi-Works Chemical Co., Ltd

website:http://www.kemiworks.com

Contact:86-27-85736489

Address:Rm. 1503, No. 164, Jianghan North Rd., Wuhan, 430022 China
SEA BRGIHT INDUSTRY CO.,LIMITED

Contact:0086 755 8622 3990

Address:Rm 17B3,GuangCaiXinTianDi Bldg,GuiMiao Rd,NanShan District,Shenzhen,China

Relevant to this article

A novel and efficient synthesis of 3,3′-benzylidenebis(4-hydroxy-6- methylpyridin-2(1H)-one) derivatives through a multi-component reaction catalyzed by L-proline

Doi:10.1071/CH08113
(2008)
Synthesis of de novo designed small-molecule inhibitors of bacterial RNA polymerase

Doi:10.1016/j.tet.2008.08.037
(2008)
Palladium-catalyzed cyclization of 3-bromopyridine-4-carbaldehyde with carbon monoxide and carboxylic acids

Doi:10.1002/jhet.5570450523
(2008)
Efficient and selective synthesis of quinoline derivatives

Doi:10.1016/j.tet.2008.08.018
(2008)
Synthesis of 3,4-dihydro-2H-imidazo-[2,1-b][1,3,4]thiadiazines

Doi:10.1007/s10593-007-0184-9
(2007)
THE FIXING ROLE OF THE tert-BUTYL GROUP IN THE CONFORMATIONAL PROPERTIES OF ACYCLIC SULPHUR COMPOUNDS. SYNTHESIS AND CONFORMATIONAL ANALYSIS OF 2-tert-BUTYLTHIODERIVATIVES OF 1-PHENYLETHANOL AND THEIR O-METHYL ANALOGS.

Doi:10.1016/S0040-4020(01)80100-9
(1989)

Article Doi