Synthesis of Macrocyclic Terpenoids by Intramolecular Cyclization. 12. Total Synthesis of Methyl Ceriferate I, a 14-Membered Ring Sesterterpene from Scale Insects

DOI: 10.1021/jo00242a018

Source and publish data:

Journal of Organic Chemistry p. 1437 - 1441 (1988)

Update date:2022-09-26

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Authors:

Kodama, Mitsuaki

Shiobara, Yoshinori

Sumitomo, Hisako

Fukuzumi, Kazuyoshi

Minami, Hiroyuki

Miyamoto, Yasuko

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Article abstract of DOI:10.1021/jo00242a018

Total synthesis of (+/-)-methyl ceriferate I (6), the methyl ester of a cembrane-type sesterterpene isolated from the wax of scale insects, was achieved by means of Wadsworth-Emmons olefination as key step.Three segments, 9, 10, and 11, were connected to

Full text of DOI:10.1021/jo00242a018

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