PHOSPHINSUBSTITUIERTE CHELATLIGANDEN XIX. DIASTEREOSELEKTIVE KOMPLEXBILDUNG MIT CHIRALEN PHOSPHINOTHIOFORMAMIDEN

DOI: 10.1016/0022-328X(86)80094-8

Source and publish data:

Journal of Organometallic Chemistry p. C30 - C34 (1986)

Update date:2022-08-05

Topics:

Authors:

Kunze, U.

Jawad, H.

Burghardt, R.

Tittmann, R.

Kruppa, V.

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Article abstract of DOI:10.1016/0022-328X(86)80094-8

We suggest three ways for the synthesis of chiral phosphinothiofprmamide ligands with an asymmetric centre at carbon or phosphorus.The stereoselectivity of the complex formation with CpM(CO)3Cl (M = Mo, W) is controlled by thermodynamic and kinetic factor

Full text of DOI:10.1016/0022-328X(86)80094-8

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