Synthesis p. 727 - 730 (1986)
Update date:2022-08-04
Topics:
Evans, Robert D.
Schauble, J. Herman
I(1+)(Collidine)2BF4(1-)/DMSO has been found to be a convenient reagent for the direct conversion of alkenes to α-iodocarbonyl compounds.Using conformationally biased alkenes, the reactions proceed stetreospecifically giving axial iodoketones.Application of the reagent in reactions with unsaturated carbohydrates provides a unique method for the conversion of certain glycals to their corresponding α-iodo-α,β-unsaturated lactones.
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(2007)Doi:10.1016/j.jfluchem.2016.11.008
(2017)Doi:10.1016/S0040-4039(00)85382-4
(1986)Doi:10.1021/ja805025w
(2008)
