Organic Letters p. 5123 - 5126 (2008)
Update date:2022-08-05
Topics:
Chapelat, Julien
Buss, Axel
Chougnet, Antoinette
Woggon, Wolf-D.
(Chemical Equation Presented) A diastereoselective synthesis of α-tocopherol 1 (93% de) was achieved via two key steps, (i) a highly diastereoselective Shi epoxidation of a trisubstituted alkene and (ii) an acid supported, "anti-Baldwin" epoxide ring opening under inversion of configuration leading to the 6-membered chromanol ring.
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Doi:10.1039/b806451b
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(2015)Doi:10.1246/bcsj.30.976
(1957)Doi:10.1021/ja8056908
(2008)Doi:10.1055/s-2008-1078011
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(2008)
