Organo cerium reagents in organic chemistry: General method of synthesis of alkyl substituted 1,3-diols by RLi-CeCl3 addition to β-hydroxyketones

DOI: 10.1016/0040-4039(96)00246-8

Source and publish data:

Tetrahedron Letters p. 2293 - 2296 (1996)

Update date:2022-08-05

Topics:

Authors:

Bartoli, Giuseppe

Bosco, Marcella

Van Beek, Jacco

Sambri, Letizia

Marcantoni, Enrico

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Article abstract of DOI:10.1016/0040-4039(96)00246-8

Organocerium compounds (RLi-CeCl₃) are able to transfer an alkyl group to the carbonylic function of a β-hydroxyketone giving alkyl substituted 1,3-diols in excellent yields. The use of these not sophisticated reagents is essential to depress u

Full text of DOI:10.1016/0040-4039(96)00246-8

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