(2-CHLOROVINYL)CHLOROCARBENES: GENERATION AND REACTIONS WITH ALKENES

DOI: 10.1007/BF00961043

Source and publish data:

Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 2228 - 2234 (1991)

Update date:2022-07-29

Topics: Cyclopropanation Metal-Catalyzed Reactions Insertion into C-H Bonds Addition to Alkenes Cycloadditions

Authors:

Shavrin, K.N.

Okonnishnikova, G.P.

Nefedov, O.M.

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Article abstract of DOI:10.1007/BF00961043

The treatment of Z-1,1,3-trichloro-4,4-dimethyl-2-pentene (Ia) with t-C4H9OK in boiling hexane or benzene gave rise to (Z-2-chloro-3,3-dimethyl-1-butenyl)chlorocarbene (IVa), which reacted with alkenes to give the cyclopropane derivatives (V) in 44-57perc

Full text of DOI:10.1007/BF00961043

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