Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 2228 - 2234 (1991)
Update date:2022-07-29
Topics: Cyclopropanation Metal-Catalyzed Reactions Insertion into C-H Bonds Addition to Alkenes Cycloadditions
Shavrin, K.N.
Okonnishnikova, G.P.
Nefedov, O.M.
The treatment of Z-1,1,3-trichloro-4,4-dimethyl-2-pentene (Ia) with t-C4H9OK in boiling hexane or benzene gave rise to (Z-2-chloro-3,3-dimethyl-1-butenyl)chlorocarbene (IVa), which reacted with alkenes to give the cyclopropane derivatives (V) in 44-57perc
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