Study on the Reactions of the Dinitrogen Complexes trans- (M = Mo or W) with Ethyldiazoacetate: Formation of an Azo Compound and of a Phosphazene Species

DOI: 10.1007/BF00810890

Source and publish data:

Monatshefte fur Chemie p. 429 - 436 (1986)

Update date:2022-07-31

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Authors:

Herrmann, Rudolf

Pombeiro, Armando J. L.

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Article abstract of DOI:10.1007/BF00810890

Complex trans- (dppe = Ph2PCH2CH2PPh2) reacts with NN = CHCOOEt in benzene solution to afford benzene-azomethane, Ph-N=N-CH3, as the main organic product.However, the phosphazene species Ph2P(N2CHCOOEt)(CH2CH2)P(N2CHCOOEt)Ph2 is formed by irradiating a THF solution of trans- in the presence of ethyldiazoacetate; in moist solution, the phosphazene bonds undergo a partial hydrolysis, and the phosphonium species ²⁺ appears to be formed. - Keywords: Catalysis; Dinitrogen complexes; Ethyldiazoacetate

Full text of DOI:10.1007/BF00810890

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