Study on the Reactions of the Dinitrogen Complexes trans- (M = Mo or W) with Ethyldiazoacetate: Formation of an Azo Compound and of a Phosphazene Species

DOI: 10.1007/BF00810890

Source and publish data:

Monatshefte fur Chemie p. 429 - 436 (1986)

Update date:2022-07-31

Topics:

Authors:

Herrmann, Rudolf

Pombeiro, Armando J. L.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1007/BF00810890

Complex trans- (dppe = Ph2PCH2CH2PPh2) reacts with NN = CHCOOEt in benzene solution to afford benzene-azomethane, Ph-N=N-CH3, as the main organic product.However, the phosphazene species Ph2P(N2CHCOOEt)(CH2CH2)P(N2CHCOOEt)Ph2 is formed by irradiating a THF solution of trans- in the presence of ethyldiazoacetate; in moist solution, the phosphazene bonds undergo a partial hydrolysis, and the phosphonium species ²⁺ appears to be formed. - Keywords: Catalysis; Dinitrogen complexes; Ethyldiazoacetate

Full text of DOI:10.1007/BF00810890

Products guided by the article

Product name:C₃₄H₃₆N₄O₄P₂

Cas No:108175-64-0

R&D Labs maybe for 108175-64-0

Changzhou Hopschain Chemical Co.,Ltd

website:http://www.hopschem.cn/products.html

Contact:86-519-85528066

Address:Room 710, Unit A, Xingbei Development Mansion, Tongjiang Road, Changzhou City,213000, China
GIHI CHEMICALS CO.,LIMITED

Contact:+86-571-86217390

Address:No.567 Dengcai Street,Sandun,Westlake District,Hangzhou310030,Zhejiang,China.
Hangzhou Showland Technology Co., Ltd.

Contact:86-571-88920516

Address:ROOM2118,NO.553,WENSAN ROAD,HANGZHOU,CHINA
Shanghai UCHEM Inc.

Contact:+86-21-56338808

Address:799 Dunhuang Road, Putuo
Yantai Derun Liquid Crystal Materials Co. Ltd.

website:http://www.ytderun.com

Contact:86-535-6300169

Address:ROOM 90, XIANGFU STREET, FUSHAN NEW-HIGH-TECH IDUSTRY ZONE, YANTAI

Relevant to this article

Rationally designed pincer-type heck catalysts bearing aminophosphine substituents: Pd^IV intermediates and palladium nanoparticles

Doi:10.1002/chem.200800441
(2008)
Synthesis of (-)-(Z)-deoxypukalide

Doi:10.1002/anie.200802703
(2008)
Synthesis of a highly potent analogue of prostacyclin, (-)-5-methyleneisocarbacyclin

Doi:10.1248/cpb.34.4403
(1986)
The design, synthesis, and evaluation of coumarin ring derivatives of the novobiocin scaffold that exhibit antiproliferative activity

Doi:10.1021/jo801312r
(2008)
Synthesis of pyrenolide D analogues

Doi:10.1055/s-2008-1077976
(2008)
A NATURAL PRODUCT WAS SHOWN TO BE OF LOW OPTICAL PURITY: SYNTHESIS OF (2S,5R,6E,8E)-2,5-EPOXY-6,8-MEGASTIGMADIENE, ITS (6Z,8E)-ISOMER AND (2S,6R,7S,8E)-2,7-EPOXY-4,8-MEGASTIGMADIENE, THE CONSTITUENTS OF OSMANTHUS ABSOLUTE

Doi:10.1016/S0040-4020(01)90549-6
(1986)

Article Doi