Tetrahedron p. 2643 - 2646 (1986)
Update date:2022-07-31
Topics:
Mori, Kenji
Tamura, Hiroshi
The title compounds were synthesized from (S)-3-hydroxy-2,2-dimethylcyclohexanone. (6E,8E)-2,5-Epoxy-6,8-megastigmadiene isolated as a minor constituent of Osmanthus absolute was shown to be of only ca. 11percent e.e. enriched in (2S,5R)-(+)-isomer.
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