Azo Anions in Synthesis. t-Butylhydrazones as Acyl-anion Equivalents

DOI: 10.1039/c39830001040

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1040 - 1041 (1983)

Update date:2022-08-03

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Authors:

Adlington, Robert M.

Baldwin, Jack E.

Bottaro, Jeffrey C.

Perry, Matthew W. D.

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Article abstract of DOI:10.1039/c39830001040

The lithium salts of aldehyde t-butylhydrazones react with electrophiles (aldehydes, ketones, alkyl halides) to form C-trapped t-butylazo compounds; isomerisation and hydrolyse gave α-hydroxy ketones and ketones in good yields, thereby providing a convenient new acyl-anion equivalent.

Full text of DOI:10.1039/c39830001040

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