Journal of the Chemical Society. Chemical communications p. 1040 - 1041 (1983)
Update date:2022-08-03
Topics:
Adlington, Robert M.
Baldwin, Jack E.
Bottaro, Jeffrey C.
Perry, Matthew W. D.
The lithium salts of aldehyde t-butylhydrazones react with electrophiles (aldehydes, ketones, alkyl halides) to form C-trapped t-butylazo compounds; isomerisation and hydrolyse gave α-hydroxy ketones and ketones in good yields, thereby providing a convenient new acyl-anion equivalent.
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Doi:10.1002/jhet.5570230560
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