Synthesis and 13C, 29Si, 199Hg nuclear magnetic resonance spectroscopy of alkynyl(trimethylsilyl)mercurials

DOI: 10.1016/0584-8539(86)80063-0

Source and publish data:

Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy p. 1107 - 1112 (1986)

Update date:2022-07-29

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Authors:

Sebald, Angelika

Wrackmeyer, Bernd

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Article abstract of DOI:10.1016/0584-8539(86)80063-0

Alkynyl(trimethylsilyl)mercurials are formed by a fast and quantitative reaction between bis(alkynyl)- and bis(trimethylsilyl)mercury in chloroform or benzene at ambient temperature.They decompose slowly in solution to alkynyltrimethylsilanes and mercury. 13C, 29Si, 199Hg NMR data serve for the characterization.The polarizability of the Hg-Si bond and the great polarizing ability of the alkynyl group is clearly reflected by the NMR data.

Full text of DOI:10.1016/0584-8539(86)80063-0

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