Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy p. 1107 - 1112 (1986)
Update date:2022-07-29
Topics:
Sebald, Angelika
Wrackmeyer, Bernd
Alkynyl(trimethylsilyl)mercurials are formed by a fast and quantitative reaction between bis(alkynyl)- and bis(trimethylsilyl)mercury in chloroform or benzene at ambient temperature.They decompose slowly in solution to alkynyltrimethylsilanes and mercury. 13C, 29Si, 199Hg NMR data serve for the characterization.The polarizability of the Hg-Si bond and the great polarizing ability of the alkynyl group is clearly reflected by the NMR data.
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Doi:10.1002/hlca.201100256
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(1987)
