CHIRAL INDUCTION IN PHOTOCHEMICAL REACTIONS-V. REGIO- AND DIASTEREOSELECTIVITY IN THE PHOTOCHEMICAL CYCLOADDITION OF CHIRAL CYCLENONE-3-CARBOXYLATE WITH 1,1'-DIETHOXYETHENE

DOI: 10.1016/S0040-4020(01)87320-8

Source and publish data:

Tetrahedron p. 3547 - 3558 (1986)

Update date:2022-07-31

Topics:

Authors:

Herzog, Heinz

Koch, Hartmut

Scharf, Hans-Dieter

Runsink, Jan

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Article abstract of DOI:10.1016/S0040-4020(01)87320-8

The chiral cyclenone-3-carboxylate 5-12 induce high regio - but only fair diastereoselectivities in the photochemical <2+2> cycloaddition with 1,1'-diethoxyethene 23.Cyclohex-2-ene-1-one-3-carboxylates gain higher diastereoselectivites compared to the rin

Full text of DOI:10.1016/S0040-4020(01)87320-8

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Product name:cyclopentene (2)-1-one-3<(+) (1S, 2R, 5R)-5-methyl-2-(1-methyl-1-phenylethyl)-cyclohexyl>-carboxylate

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