TOTAL SYNTHESIS OF TYLONOLIDE, THE AGLYCONE OF THE 16-MEMBERED RING MACROLIDE TYLOSIN, FROM D-GLUCOSE. SELECTIVE APPLICATION OF MPM AND DMPM PROTECTING GROUPS FOR HYDROXY FUNCTIONS

DOI: 10.1016/S0040-4039(00)84872-8

Source and publish data:

Tetrahedron Letters p. 3651 - 3654 (1986)

Update date:2022-08-04

Topics:

Authors:

Tanaka, Tatsuyoshi

Yuji, Oikawa

Hamada, Tatsuo

Yonemitsu, Osamu

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Article abstract of DOI:10.1016/S0040-4039(00)84872-8

Segments i (C11-C17) and ii (C1-C10), synthesized from D-glucose by employing some stereoselective reactions and benzyl-type protecting groups, were esterified and cyclized to the 16-membered enone , which was readily converted to tylonolide, the aglycone

Full text of DOI:10.1016/S0040-4039(00)84872-8

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