DIELS-ALDER CYCLIZATION OF 2,8,10-UNDECATRIENALS AS A ROUTE TO 1,2,3,4,4a,5,6,8a-OCTAHYDRONAPHTHALENES

DOI: 10.1016/S0040-4020(01)90578-2

Source and publish data:

Tetrahedron p. 2893 - 2902 (1986)

Update date:2022-08-05

Topics:

Authors:

Marshall, James A.

Audia, James E.

Grote, Jonathan

Shearer, Barry G.

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Article abstract of DOI:10.1016/S0040-4020(01)90578-2

2,8,10-Undecatrienals have been found to undergo facile Diels-Alder cyclization upon treatment with alkylaluminum chlorides in methylene chloride at low temperature.The reaction is highly endo-selective.Protected alcohol substituents at the C-4 and C-7 po

Full text of DOI:10.1016/S0040-4020(01)90578-2

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