ORGANOMETALLIC COMPLEXES WITH RSSR LIGANDS: A NEW SYNTHETIC METHOD

DOI: 10.1016/0022-328X(86)80232-7

Source and publish data:

Journal of Organometallic Chemistry p. 193 - 198 (1986)

Update date:2022-07-29

Topics:

Authors:

Treichel, P. M.

Schmidt, M. S.

Nakagaki, P. C.

Rublein, E. K.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-328X(86)80232-7

Reactions of BF4 with metal thiolate complexes have been used to prepare new complexes with coordinated organic disulfide ligands.Complexes prepared include BF4 (L=CO,PPh3, PPh2Me, PPh2OMe, P(OPh)3), BF4 and BF4.A molybdenum analogue of the last compound and BF4 were identified in solution as products of this type of reaction, but these species were unstable and could not be isolated.Isomerization of (PhSSMe)>BF4 upon heating was noted.This synthetic method ia easy and versatile, and is a useful alternative to other known routes to this type of complex.

Full text of DOI:10.1016/0022-328X(86)80232-7

Products guided by the article

Product name:[(C₅H₅)Fe(CO)(P(C₆H₅)2CH₃)(C₆H₅SSCH₃)]⁽¹⁺⁾*BF₄^(1-)=[(C₅H₅)Fe(CO)(P(C₆H₅)2CH₃)(C₆H₅SSCH₃)]BF₄

Cas No:108588-80-3

R&D Labs maybe for 108588-80-3

Anhui Sunsing Chemicals Co.,Ltd

website:http://www.sunsingchem.com

Contact:0086-566-2023179

Address:Jin An industry park, Chizhou economic technical development zone, Anhui
RongCheng K&S Chemical Co.,Ltd

Contact:0631-7336369

Address:rongcheng ,shandong province china
Zhengzhou Yuanli Biological Technology Co., Ltd.

Contact:+86-371-67897870/67897895

Address:No. 38, Qingyang Street, Zhengzhou, Henan, China
PINGYUAN SIHUAN PHARMACEUTICAL CO., LTD

Contact:+86-531-55696072

Address:#2766,yinxiu Road, Economic Development Zone, Pingyuan Country, Shandong Province, China.
Shandong Wanda Organosilicon New Material Co., Ltd

Contact:+86-21-54177116;54302881

Address:R1318 Greenland No. 3 Lane 58 Xinjian East Rd., Minhang

Relevant to this article

Three-dimensional intramolecular exchange interaction in a curved and nonalternant π-conjugated system: Corannulene with two phenoxyl radicals

Doi:10.1002/anie.200906666
(2010)
Conjugate addition of amines to chiral 3-aziridin-2-yl-acrylates

Doi:10.1016/j.tetlet.2010.02.087
(2010)
A novel chiral manganese-tetraamide macrocycle complex covalently attached to magnetite as recyclable catalyst for aerobic asymmetric epoxidation of olefins

Doi:10.1016/j.ica.2017.03.019
(2017)
A hydroboration route to geminal P/B frustrated Lewis pairs with a bulky secondary phosphane component and their reaction with carbon dioxide

Doi:10.1039/c7dt02315d
(2017)
Microbiological Transformations. 19. Asymmetric Dihydroxylation of the Remote Double Bond of Geraniol: A Unique Stereochemical Control Allowing Easy Access to Both Enantiomers of Geraniol-6,7-diol

Doi:10.1021/jo00012a010
(1991)
Asymmetrie direct vinylogous aldol reaction of furanone derivatives catalyzed by an axially chiral guanidine base

Doi:10.1002/anie.200906647
(2010)

Article Doi