ORGANOMETALLIC COMPLEXES WITH RSSR LIGANDS: A NEW SYNTHETIC METHOD

DOI: 10.1016/0022-328X(86)80232-7

Source and publish data:

Journal of Organometallic Chemistry p. 193 - 198 (1986)

Update date:2022-07-29

Topics:

Authors:

Treichel, P. M.

Schmidt, M. S.

Nakagaki, P. C.

Rublein, E. K.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-328X(86)80232-7

Reactions of BF4 with metal thiolate complexes have been used to prepare new complexes with coordinated organic disulfide ligands.Complexes prepared include BF4 (L=CO,PPh3, PPh2Me, PPh2OMe, P(OPh)3), BF4 and BF4.A molybdenum analogue of the last compound and BF4 were identified in solution as products of this type of reaction, but these species were unstable and could not be isolated.Isomerization of (PhSSMe)>BF4 upon heating was noted.This synthetic method ia easy and versatile, and is a useful alternative to other known routes to this type of complex.

Full text of DOI:10.1016/0022-328X(86)80232-7

Products guided by the article

Product name:[(C₅H₅)Fe(CO)(P(C₆H₅)2CH₃)(C₆H₅SSCH₃)]⁽¹⁺⁾*BF₄^(1-)=[(C₅H₅)Fe(CO)(P(C₆H₅)2CH₃)(C₆H₅SSCH₃)]BF₄

Cas No:108588-80-3

R&D Labs maybe for 108588-80-3

Zhengzhou HQ Material Co.,Ltd

Contact:+86-371-67759225

Address:No.32, Jinsuo Road, High-tech Zone
Shanghai Yuantai Chemical Products Co., Ltd

Contact:021--66129803

Address:Chengyin Road,Shanghai,China
Shijiazhuang Haotian Chemical Co., Ltd.

Contact:86-311-85044374

Address:293 Donggang Road
Maithili Life Sciences

Contact:+91 9963263336

Address:Plot#146A, IDA Mallapur, Hyderabad - 500072
SHANXI JINJIN CHEMICAL INDUSTRIAL CO.,LTD

website:http://www.jinjingroup.com

Contact:86-574-13989382828

Address:Economic And Technological Development Zone,Hejin?City,Shanxi Province?,China

Relevant to this article

Three-dimensional intramolecular exchange interaction in a curved and nonalternant π-conjugated system: Corannulene with two phenoxyl radicals

Doi:10.1002/anie.200906666
(2010)
Conjugate addition of amines to chiral 3-aziridin-2-yl-acrylates

Doi:10.1016/j.tetlet.2010.02.087
(2010)
A novel chiral manganese-tetraamide macrocycle complex covalently attached to magnetite as recyclable catalyst for aerobic asymmetric epoxidation of olefins

Doi:10.1016/j.ica.2017.03.019
(2017)
A hydroboration route to geminal P/B frustrated Lewis pairs with a bulky secondary phosphane component and their reaction with carbon dioxide

Doi:10.1039/c7dt02315d
(2017)
Microbiological Transformations. 19. Asymmetric Dihydroxylation of the Remote Double Bond of Geraniol: A Unique Stereochemical Control Allowing Easy Access to Both Enantiomers of Geraniol-6,7-diol

Doi:10.1021/jo00012a010
(1991)
Asymmetrie direct vinylogous aldol reaction of furanone derivatives catalyzed by an axially chiral guanidine base

Doi:10.1002/anie.200906647
(2010)

Article Doi