ORGANOMETALLIC COMPLEXES WITH RSSR LIGANDS: A NEW SYNTHETIC METHOD

DOI: 10.1016/0022-328X(86)80232-7

Source and publish data:

Journal of Organometallic Chemistry p. 193 - 198 (1986)

Update date:2022-07-29

Topics:

Authors:

Treichel, P. M.

Schmidt, M. S.

Nakagaki, P. C.

Rublein, E. K.

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Article abstract of DOI:10.1016/0022-328X(86)80232-7

Reactions of BF4 with metal thiolate complexes have been used to prepare new complexes with coordinated organic disulfide ligands.Complexes prepared include BF4 (L=CO,PPh3, PPh2Me, PPh2OMe, P(OPh)3), BF4 and BF4.A molybdenum analogue of the last compound and BF4 were identified in solution as products of this type of reaction, but these species were unstable and could not be isolated.Isomerization of (PhSSMe)>BF4 upon heating was noted.This synthetic method ia easy and versatile, and is a useful alternative to other known routes to this type of complex.

Full text of DOI:10.1016/0022-328X(86)80232-7

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Product name:[(C₅H₅)Fe(CO)(P(C₆H₅)2CH₃)(C₆H₅SSCH₃)]⁽¹⁺⁾*BF₄^(1-)=[(C₅H₅)Fe(CO)(P(C₆H₅)2CH₃)(C₆H₅SSCH₃)]BF₄

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