Microbiological Transformations. 19. Asymmetric Dihydroxylation of the Remote Double Bond of Geraniol: A Unique Stereochemical Control Allowing Easy Access to Both Enantiomers of Geraniol-6,7-diol

DOI: 10.1021/jo00012a010

Source and publish data:

Journal of Organic Chemistry p. 3814 - 3817 (1991)

Update date:2022-07-29

Topics: Synthesis NMR Tetrahedron Lett. J. Org. Chem. Hz Found

Authors:

Zhang, X. M.

Archelas, A.

Furstoss, R.

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Article abstract of DOI:10.1021/jo00012a010

The microbiological oxygenation of the geraniol N-phenylcarbamate 1 by Aspergillus niger is described, which leads regiospecifically to a formal dihydroxylation of its C(6)=C(7) double bond.By use of different pH values of the incubation medium, it is pos

Full text of DOI:10.1021/jo00012a010

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