ALKYLATION OF STABILIZED ACETYLIDES IN DMSO. PREPARATION OF α,β-ACETYLENIC ALCOHOLS AND ACETALS.

DOI: 10.1016/S0040-4039(00)85233-8

Source and publish data:

Tetrahedron Letters p. 5445 - 5448 (1986)

Update date:2022-08-03

Topics:

Authors:

Chong, J. Michael

Wong, Susanna

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)85233-8

Stabilized terminal acetylenes 1 2OTHP, Ph, CH(OET)₂> may be converted into lithioacetylides and readily alkylated with 1 alkyl halides in DMSO to afford functionalized disubstitued acetylenes.

Full text of DOI:10.1016/S0040-4039(00)85233-8

Products guided by the article

Product name:2-(5-Methyl-hex-2-ynyloxy)-tetrahydro-pyran

Cas No:108604-36-0

R&D Labs maybe for 108604-36-0

Shenzhen Sunrising Industry Co., ltd.

Contact:+86 755 86571158 / 86571159 / 86571160

Address:2108 ZHENYE INT. BUSINESS CENTER,NO.3101-90 QIANHAI RD, NANSHAN,SHENZHEN, CHINA
Xi'an North Information Industry Co., Ltd. Weilv Chemical Department

Contact:+86-29-88156413

Address:Jixiang Road 99 Xi'an Shaanxi Province
Nanjing Ruizhi Industry & Technologh Co.，Ltd.

Contact:+86-25-86808110

Address:441-4-A5,NO.12 Longzang Avenue,Yuhuatai District,210039,Nanjing
Chuzhou Baiao Biologhy S&T Co., Ltd.

Contact:+86-25-83212599；+86-25-83212699 13705185959

Address:Room 905, Tianzheng International Platza, No.399, Zhongyang Road ,Nanjing, Jiangsu Province, China
Quzhou Hopemax Chemical Technology Co.Ltd

Contact:86-570-3036007

Address:Room 801,Building 2,Wealth Center,No.51,Xujiang Road,Quzhou,China.

Relevant to this article

Diorganotin(IV) complexes with 2-benzoylpyridine and 2-acetylpyrazine N(4)-phenylthiosemicarbazones: Synthesis, crystal structures and biological activities

Doi:10.1016/j.jorganchem.2010.10.011
(2011)
Synthesis of functionalized pyroglutamic acids, part 2: The stereoselective condensation of multifunctional groups with chiral levulinic acids

Doi:10.1055/s-2008-1078211
(2008)
Characterization of a novel polyphenol-specific oligoxyloside transfer reaction by a family 11 xylanase from Bacillus sp. KT12

Doi:10.1271/bbb.80116
(2008)
Disruption of redox homeostasis with synchronized activation of apoptosis highlights the antifilarial efficacy of novel piperine derivatives: An in vitro mechanistic approach

Doi:10.1016/j.freeradbiomed.2021.04.026
(2021)
A new route to 2,5-diamino-4,6-dichloropyramidine, a key precursor of 9-substituted guanines

Doi:10.1055/s-1990-26949
(1990)
STRUCTURE AND DIASTEREOSELECTIVITY OF THE α-HYDROXYLATION OF CHIRAL ESTER ENOLATES BY MOLYBDENUM PEROXO COMPLEX

Doi:10.1016/S0040-4039(00)84894-7
(1986)

Article Doi