ALKYLATION OF STABILIZED ACETYLIDES IN DMSO. PREPARATION OF α,β-ACETYLENIC ALCOHOLS AND ACETALS.

DOI: 10.1016/S0040-4039(00)85233-8

Source and publish data:

Tetrahedron Letters p. 5445 - 5448 (1986)

Update date:2022-08-03

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Authors:

Chong, J. Michael

Wong, Susanna

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Article abstract of DOI:10.1016/S0040-4039(00)85233-8

Stabilized terminal acetylenes 1 2OTHP, Ph, CH(OET)₂> may be converted into lithioacetylides and readily alkylated with 1 alkyl halides in DMSO to afford functionalized disubstitued acetylenes.

Full text of DOI:10.1016/S0040-4039(00)85233-8

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