STRUCTURE AND DIASTEREOSELECTIVITY OF THE α-HYDROXYLATION OF CHIRAL ESTER ENOLATES BY MOLYBDENUM PEROXO COMPLEX

DOI: 10.1016/S0040-4039(00)84894-7

Source and publish data:

Tetrahedron Letters p. 3999 - 4002 (1986)

Update date:2022-08-03

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Authors:

Gamboni, Remo

Tamm, Christoph

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Article abstract of DOI:10.1016/S0040-4039(00)84894-7

Scope and limitations of the diastereoselective α-hydroxylation of chiral ester enolates by MoO5.Py.HMPT were investigated.An improved synthesis of natural (-)-verrucarinolactone ((-)-(2S,3R)-2-hydroxy-3-methyl-pentanolide) is described.

Full text of DOI:10.1016/S0040-4039(00)84894-7

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