Journal of Organic Chemistry p. 9320 - 9325 (2008)
Update date:2022-08-05
Topics:
Takagi, Ryukichi
Inoue, Yuta
Ohkata, Katsuo
(Chemical Equation Presented) The construction of a highly functionalized adamantane core of plukenetione-type polycyclic polyprenylated acylphloroglucinols (PPAPs) is described. The method features the construction of the bicyclo[3.3.1]nonane core (3) by successive Michael reactions and the construction of the adamantane core of plukenetione-type PPAPs by acid-catalyzed cyclization of a bicyclo[3.3.1]nonane precursor (2).
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Doi:10.1039/a707210d
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