Synthesis p. 318 - 320 (1987)
Update date:2022-08-03
Topics:
Barluenga, Jose
Alvarez, Flora
Concellon, Jose M.
Bernad, Pablo
Yus, Miguel
The reaction of different lithium ketone enolates with α-chloro carbonyl compounds followed by in situ reduction with lithium aluminium hydride or deuteride and final lithiation with lithium powder leads to the corresponding homoallylic or 1-deuterio homoallylic alcohols in a regioselective manner.
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