Metal-catalyzed cyclopropene rearrangements for benzannulation: Evaluation of an anthraquinone synthesis pathway and reevaluation of the parallel approach via carbene-chromium complexes

DOI: 10.1021/ja00095a014

Source and publish data:

Journal of the American Chemical Society p. 7108 - 7122 (1994)

Update date:2022-07-29

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Authors:

Semmelhack

Ho, Suzzy

Cohen Cohen

Steigerwald

Lee Lee

Gilbert, Adam M.

Wutff, William D.

Ball, Richard G.

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Article abstract of DOI:10.1021/ja00095a014

The reaction of 3-arylcyclopropenes with Cr(CO)₆ and Mo(CO)₆ produces naphthols, in an example of metal-promoted benzannulation. Substituents at C- 3 (in addition to aryl) have a strong effect on the success of the process: 3-H deriv

Full text of DOI:10.1021/ja00095a014

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