A General SRN1-Based Method for Total Synthesis of Unsymmetrically Hydroxylated 2,2'-Binaphtalenes

DOI: 10.1021/jo00226a030

Source and publish data:

Journal of Organic Chemistry p. 3880 - 3883 (1987)

Update date:2022-09-26

Topics:

Authors:

Beugelmans, Rene

Bois-Choussy, Michele

Tang, Qian

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00226a030

An S_RN1 reaction between 2'-haloacetophenones and 2'-acetonaphthone derived enolates is the key step in a straightforward one-pot synthesis of unsymetrically substituted 2,2'-binaphtyl derivatives 3a-j.

Full text of DOI:10.1021/jo00226a030

Products guided by the article

Product name:2,2-bis(4-acetylphenyl)-2'-acetonaphthone

Cas No:109124-63-2

R&D Labs maybe for 109124-63-2

SAGECHEM LIMITED

website:http://www.sagechem.com

Contact:+86-571-86818502

Address:Room C1301, New Youth Plaza, 8 Jia Shan Road, Hangzhou, China
Shanghai Bosman Industrial Co., Ltd

Contact:86-21-63065878-8006

Address:Rm907, No.1611, North Sichuan Road, Hongkou District, Shanghai, 200080 China
KAIYUAN CHEMICAL COMPANY LIMITED.

website:http://www.kaiyuanchem.com

Contact:+86-22-59891255/66/77

Address:B-2205, Kuangshi International Building, Yingbin Road, XiangLuo Bay Business District, Binhai New area, Tianjin, China.
Xi'an Tizan Tech & Industry Co., Ltd.

Contact:86-18629066522

Address:C3009 TANG FENG INTERNATIONAL PLAZA, NO.18 FENGHUI NAN ROAD, XI'AN HIGH TECH ZONE, 710075 CHINA.
Jinan Jiaquan Chemical Co.,Ltd

Contact:+86-531-62318366

Address:Room 502 of Yidonghuayuan No.601 Huaxin Road Licheng District Jinan China

Relevant to this article

Selective copper-mediated halogenation of aromatic rings under mild conditions

Doi:10.1002/ejic.201100489
(2011)
Efficient formation of ring structures utilizing multisite activation by indium catalysis

Doi:10.1021/ja805657h
(2008)
A regio- and diastereoselective intramolecular nitrone cycloaddition for practical 3- and 2,3-disubstituted piperidine synthesis from γ-butyrolactone

Doi:10.1021/jo8018285
(2009)
Syntheses of the P-methylase substrates of the bialaphos biosynthetic pathway

Doi:10.1021/ol802269x
(2008)
The first chemoselective tandem acylation of the Blaise reaction intermediate: A novel method for the synthesis of α-acyl-β-enamino esters, key intermediate for pyrazoles

Doi:10.1039/b813369g
(2008)
Terminal hydride in [FeFe]-hydrogenase model has lower potential for H ₂ production than the isomeric bridging hydride

Doi:10.1021/ic800030y
(2008)

Article Doi