N-(Aminoethyl)cyclam: A Tetraaza Macrocycle with a Coordinating Tail (Scorpiand). Acidity Controlled Coordination of the Side Chain to Nickel(II) and Nickel(III) Cations

DOI: 10.1021/ja00251a016

Source and publish data:

Journal of the American Chemical Society p. 5139 - 5144 (1987)

Update date:2022-08-02

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Authors:

Pallavicini, Pier Sandro

Perotti, Angelo

Poggi, Antonio

Seghi, Barbara

Fabbrizzi, Luigi

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Article abstract of DOI:10.1021/ja00251a016

The novel functionalized macrocycle N-(aminoethyl)cyclam (4, L), in which a NH2CH2CH2-chain is appended to a tetraaza ring, has been prepared through a convenient route, whose key step involves the reaction of tritosylated cyclam and tosylaziridine.The ni

Full text of DOI:10.1021/ja00251a016

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