
Journal of the Chemical Society. Chemical communications p. 1608 - 1609 (1986)
Update date:2022-07-29
Topics:
Jahangir
MacLean, David B.
Brook, Michael A.
Holland, Herbert L.
3,4-Dihydroisoquinolines and 3,4-dihydro-β-carbolines react with trimethylsilyl trifluoromethanesulphonate to form complexes that react readily with the lithio derivatives of 3-cyano-4-methylpyridines; the method has been applied to the synthesis of the Alangium alkaloids, (+/-)-alangimaridine and alangimarine.
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