Helvetica Chimica Acta p. 1273 - 1286 (1986)
Update date:2022-07-31
Topics: Regioselectivity Characterization Yield Synthetic route Functionalized Deprotection Protecting group Tertiary alcohol Retrosynthetic analysis Diels-Alder Reaction Stereoselectivity Cycloaddition Catalysis Dienophile Diene Avermectins Milbemycins Hexahydrobenzofuran Macrocyclic lactone
Ireland, Robert E.
Obrecht, Daniel M.
A highly regio- and stereoselective Diels-Alder reaction between dienophiles of type I and dienes of type II (Scheme 1) gives rise to Diels-Alder adducts of type III.Upon treatment with BF3*Et2O, these adducts are smoothly converted into the corresponding
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