Total Synthesis of (+)-Galactostatin. An Illustration of the Utility of the Thiazole-Aldehyde Synthesis

DOI: 10.1021/jo00120a017

Source and publish data:

Journal of Organic Chemistry p. 4749 - 4754 (1995)

Update date:2022-08-05

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Authors:

Dondoni, Alessandro

Perrone, Daniela

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Article abstract of DOI:10.1021/jo00120a017

The natural aza sugar (+)-galactostatin (+)-1 has been prepared from D-serine by sequential installation of chiral 1C and 2C units employing thiazole-based reagents.Thus, the D-serine-derived methyl ester 3 was transformed by 2-thiazolyllithium (4) into t

Full text of DOI:10.1021/jo00120a017

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