Control of Si-C Bond Cleavage at Carbon α to Phosphorus. Suppression of Facile Protodesilylation of PPh2CH2SiMe2H by Complexation through Phosphorus to Ruthenium and the X-Ray Crystal and Molecular Structure of 6-p-cymene)Cl2(PPh2CH2SiMe2O

DOI: 10.1039/c39860001580

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1580 - 1581 (1986)

Update date:2022-08-05

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Authors:

Brost, Ron D.

Bruce, Gregg C.

Stobart, Stephen R.

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Article abstract of DOI:10.1039/c39860001580

Facile cleavage of the Si-C bond α to P in Ph2PCH2SiMe2H which is induced by HY (Y = OH, OMe, or Cl) is suppressed on complexation at Ru in 6-cym)Cl2(PPh2CH2SiMe2H)> (cym = p-cymene); instead the latter reacts where Y = OH to afford the si

Full text of DOI:10.1039/c39860001580

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