Control of Si-C Bond Cleavage at Carbon α to Phosphorus. Suppression of Facile Protodesilylation of PPh2CH2SiMe2H by Complexation through Phosphorus to Ruthenium and the X-Ray Crystal and Molecular Structure of 6-p-cymene)Cl2(PPh2CH2SiMe2O

DOI: 10.1039/c39860001580

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1580 - 1581 (1986)

Update date:2022-08-05

Topics:

Authors:

Brost, Ron D.

Bruce, Gregg C.

Stobart, Stephen R.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39860001580

Facile cleavage of the Si-C bond α to P in Ph2PCH2SiMe2H which is induced by HY (Y = OH, OMe, or Cl) is suppressed on complexation at Ru in 6-cym)Cl2(PPh2CH2SiMe2H)> (cym = p-cymene); instead the latter reacts where Y = OH to afford the si

Full text of DOI:10.1039/c39860001580

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:(Ru(CH₃C₆H₄CH(CH₃)2)Cl₂((C₆H₅)2PCH₂Si(CH₃)2OH))

Cas No:110019-84-6

R&D Labs maybe for 110019-84-6

NEWSTAR CHEM ENTERPRISE LTD.

Contact:0572-2722882

Address:1201,F3,xinghuibandao,
Synasia Inc

Contact:17316303296

Address:240 Amboy Ave
Liao Cheng All Win Chemicals Co.,LTD

Contact:86+0635-2991582

Address:Room 402,Unit 1,No.27 building.Zhong tong shi dai haoyuan,liaocheng city,Shan dong Province.China
JADECHEM NINGBO CO.,LTD.

Contact:+86-574-89075960

Address:#100 Xiang Yun Road, New High tech area, Ningbo, China
shijiazhuang alkay chemicals co..ltd(expird)

Contact:86-311-67692035

Address:2601,juntang building,qiaodong district,shijiazhuang

Relevant to this article

Synthesis of (R,R) and (S,S) bicyclo[3.3.0]octane-2,6-dione interactions between non-conjugated chromophores

Doi:10.1016/S0957-4166(00)80469-3
(1994)
Solvent-mediated generation of cobalt-cluster-stabilised propargyl cations and radicals: Allyl migration versus peroxide formation

Doi:10.1002/chem.200801402
(2008)
Synthesis of head activator (HA)-related peptides and development of HA-radioimmunoassay.

Doi:10.1248/cpb.35.2327
(1987)
A convenient synthesis of phenyl 1-chloro-1 alkenyl chalcogenides by one-pot Wittig reaction. Synthesis of selenolesters

Doi:10.1080/10426500108046648
(2001)
Direct dehydrative n-pyridinylation of amides

Doi:10.1021/jo802355d
(2009)
Synthesis and spectral feature of benzophenone-substituted thiosemicarbazones and their Ni(II) and Cu(II) complexes

Doi:10.1016/j.saa.2008.07.005
()

Article Doi