Journal of Organic Chemistry p. 4893 - 4897 (1987)
Update date:2022-08-02
Topics:
Fauve, Annie
Renard, Michel F.
Veschambre, Henri
Microbiological reduction of α,β-unsaturated carbonyl compounds is studied.Inducibility of the enone reductase system of Beauveria sulfurescens is reported.The best inducer is shown to be cyclohex-2-en-1-one.An appropriate procedure using induced resting mycelium is developed to reduce substituted cyclohexenones that are shown to be unable to induce the reducing enzyme.Optically pure trans-(2R,6R)-(-)-2,6-dimethylcyclohexan-1-one and trans-(2R,6R)-(-)-2,6-dimethylcyclohexan-1-ol are obtained from (+/-)-2,6-dimethylcyclohex-2-en-1-one along with optically pure (6S)-(-)-2,6-dimethylcyclohex-2-en-1-one.
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Doi:10.1016/0022-5088(87)90173-1
(1987)Doi:10.1016/S0040-4020(01)87797-8
(1987)Doi:10.1021/acs.orglett.7b03121
(2017)Doi:10.1016/S0040-4039(00)85073-X
(1986)Doi:10.1021/np800448t
(2009)Doi:10.1016/j.tet.2008.10.001
(2008)
