Novel stereoselective synthesis of 1-(β-D- and α -L-glycopyranosyl)-5-methyl-1H-1,2,4-triazoles

Article abstract of DOI:10.1016/S0957-4166(03)00491-9

1-(β-D- and α-L-Glycopyranosyl)-5-methyl-1H-1,2,4-triazoles 7, 13-15 were synthesized stereoselectively from the corresponding glycopyranosyl aminoguanidine nitrates 1-3 in boiling acetic anhydride or from N ¹-(acetylated β-D- or α-L-glycopyran