Cycloaddition vs. Michael Addition in the Metal Halide/Amine-Induced Reactions of α-(Alkylideneamino) Esters with Electron-Deficient Olefins

DOI: 10.1246/bcsj.62.869

Source and publish data:

Bulletin of the Chemical Society of Japan p. 869 - 874 (1989)

Update date:2022-07-29

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Authors:

Kanemasa, Shuji

Yoshioka, Manabu

Tsuge, Otohiko

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Article abstract of DOI:10.1246/bcsj.62.869

The lithiated intermediate derived from methyl 2-(benzylideneamino)propanoate and lithium bromide/triethylamine undergoes cycloaddition and Michael addition with methyl acrylate. 1,3-Dipole character of the intermediate is suggested on the basis of the pr

Full text of DOI:10.1246/bcsj.62.869

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