The Phospha-Cope Rearrangement of 4λ-Phospha-1-hexen-5-yne Derivatives

DOI: 10.1246/cl.1986.1883

Source and publish data:

Chemistry Letters p. 1883 - 1884 (1986)

Update date:2022-07-29

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Authors:

Kawashima, Takayuki

Miki, Yasuaki

Inamoto, Naoki

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Article abstract of DOI:10.1246/cl.1986.1883

The title compounds (1) were refluxed in hexanol to give the corresponding 1,4-pentadienylphosphinates, which seem to be formed via transient "phospha-allene derivatives", together with Michael adducts of alcohol to the triple bond of 1.

Full text of DOI:10.1246/cl.1986.1883

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