Tetrahedron Letters p. 5335 - 5338 (1986)
Update date:2022-07-29
Topics:
Sunay, Ustun
Fraser-Reid, Bert
A pyranodisic homologation approach to the "eastern half" of rosaramicin is described.The synthetic plan calls for two one-carbon chain extensions, but these occur at "off-template" sites where asymmetric centers are neither destroyed nor created.However,
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