REGIOSELECTIVE CONTROL OF ALLYL ANIONS WITH CADMIUM CHLORIDE: α vs. γ CONDENSATION WITH ALDEHYDES

DOI: 10.1016/S0040-4039(00)85166-7

Source and publish data:

Tetrahedron Letters p. 5193 - 5196 (1986)

Update date:2022-07-30

Topics:

Authors:

Bo, Lei Bo, Lei

Fallis, Alex G.

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Article abstract of DOI:10.1016/S0040-4039(00)85166-7

A general method for directing the condensation of allyl anions such as 2 with aldehydes preferentially to the γ position of the unsaturated nucleophile is described.The procedure employs cadmium chloride to control the regioselectivity and will facilitat

Full text of DOI:10.1016/S0040-4039(00)85166-7

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