
Tetrahedron Letters p. 6841 - 6844 (1993)
Update date:2022-07-30
Topics: Dihydrofurans α-Diazoketones Donor-acceptor cyclopropanes
Lund, Elizabeth A.
Kennedy, Isaac A.
Fallis, Alex G.
The direct synthesis of dihydrofurans 7, 11, and 23-25 from α-diazoketones 3, 8, and 20-22 is described. The cyclopropane intermediates generated upon treatment of the α-diazoketones with metal catalysts in the presence of ethyl vinyl ether rearranged spo
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