Substitutions Selectives de Carbonyles dans les Complexes Polynucleaires VI. Sructures et Proprietes des Complexes Dithioester-Fe2(CO)5L

DOI: 10.1016/0022-328X(86)80438-7

Source and publish data:

Journal of Organometallic Chemistry p. 201 - 210 (1986)

Update date:2022-08-02

Topics:

Authors:

Lagadec, Armelle

Misterkiewicz, Boguslaw

Patin, Henri

Mousser, Abdelhamid

Marouille, Jean-Yves Le

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-328X(86)80438-7

The binuclear complexes 1(C(S)SR²>Fe2(CO)5L (L= CO) obtained by complexation of dithioesters, react under thermal activation with ligands such as L= P(OMe)3, CNR, PHPh2 to afford exclusively monosubstituted products.A single crystal X-ray structure determination of the complex, Fe2(CO)5P(OMe)3 shows the regiospecificity of monosubstitution at the metal atom not bonded to the functional carbon atom. 13C and 31P studies show interesting dynamic behaviour for the complexes with L= P(OMe)3.

Full text of DOI:10.1016/0022-328X(86)80438-7

Products guided by the article

Product name:(CO)3FeC(S)(CH(CH₃)2)S(CH₃)Fe(CO)2P(CH₃)2C₆H₅

Cas No:110282-16-1

R&D Labs maybe for 110282-16-1

KODI CHEMICAL CO., LTD

Contact:021

Address:Pudong
SINFACHEM LIMITED

Contact:86-25-84683399

Address:605, Phoenix Herui Plaza, No.389, South Taiping Road, Nanjing, China 210002
Jiangsu Fengshan Group Co., Ltd.

Contact:86-25-86558671

Address:1903,Central International Mansion 105-6 North Zhongshan Road, Nanjing, China
Anhui Gusheng Import&Export CO.,LTD

Contact:86-551-63662296

Address:Jinzhai Road NO.162 ,hefei, china
Nowa pharmaceuticals Co., LTD

Contact:86-512-69362780,69362785

Address:No.69 Weixin Road,Weiting Town,Suzhou Industrial Park

Relevant to this article

Synthesis and characterization of N-benzoyl-N′-carboxyalkyl substituted thiourea derivatives

Doi:10.1080/10426500307952
(2003)
STEREOCHEMISTRY OF LARDOLURE. THE AGGREGATION PHEROMONE OF THE ACARID MITE, LARDOGLYPHUS KONOI

Doi:10.1016/S0040-4020(01)88158-8
(1986)
Rare-earth metal hydroxylamide complexes

Doi:10.1039/b810234a
(2008)
Synthesis and biological evaluation of phenoxyacetic acid derivatives as novel free fatty acid receptor 1 agonists

Doi:10.1016/j.bmc.2014.11.016
(2015)
Effect of the trifluoroacetyl group on the direction of the recyclization of the pyrazine ring in 6-trifluoroacetylpyrrolo[1,2-a]pyrazinium salts

Doi:10.1007/s10593-007-0225-4
(2007)
Discovery of a Novel Series of Tankyrase Inhibitors by a Hybridization Approach

Doi:10.1021/acs.jmedchem.7b00883
(2017)

Article Doi