The First Example of a d3-d3 Dinuclear Compound containing Four-co-ordinate Metal Atoms sharing a Pair of Bridging Ligands: tO)2W(μ-PPh2)>2

DOI: 10.1039/c39870000845

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 845 - 847 (1987)

Update date:2022-08-04

Topics:

Authors:

Buhro, William E.

Chisholm, Malcolm H.

Folting, Kirsten

Eichhorn, Bryan W.

Huffman, John C.

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Article abstract of DOI:10.1039/c39870000845

(p-Tolyl)(Bu^tO)2W<*>W(OBu^t)2(p-tolyl) and Ph2PH (2 equiv.) react in hydrocarbon solvents to give toluene (2 equiv.) and <(Bu^tO)2W(μ-PPh2)>2 which in the solid state contains a puckered W2P2 moiety, W-W 2.59 Angstroem; in solution the W2(μ-PPh2)2 moiety is undergoing rapid inversion on the n.m.r. time-scale.

Full text of DOI:10.1039/c39870000845

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